Aba is a politically volatile, economically vibrant but environmentally poor city that is a microcosm of social conditions in the Nigerian urban informal economy. Hence, this study interrogates the social sustainability of waste picking in the city, using a hybrid of political economy and sustainable livelihoods frameworks to explicate social conditions of labour in the waste economy in relation to state/institutional policies. A mixed-methods approach was utilised, and findings indicate that a cocktail of conditions affect waste picking.